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The “A” groups are the ones in the s and p block. That is, group IA starts with Hydrogen, group VIA starts with oxygen, and group VIIA starts with fluorine. The “B” groups are in the d block. The first one is IIIB, and it increases to VIIIB. Group VIIIB encompasses everything in the iron-, cobalt-, and nickel- groups. Finally, group IB starts with copper and group IIB starts with zinc. So, if you read across the periodic table, the groups go in this order:
IA, IIA, IIIB, IVB, VB, VIB, VIIB, VIIIB, VIIIB, VIIIB, IB, IIB, IIIA, IVA, VA, VIA, VIIA, VIIIA (or “0”)
The electron configuration tells you which group it’s in – for example, [Ar]4s23d3 refers to an element in the d block, with 5 valence electrons (2+3 = 8), so it must be group VB (this would be for vanadium, by the way).
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